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Due to its unsurpassed capability to engage in various sp hybridizations or orbital mixings, carbon may contribute in expanding solid‐state nitrogen chemistry by allowing for different complex anions, such as the known NCN2− carbodiimide unit, the so far unknown CN35− guanidinate anion, and the likewise unknown CN48− ortho‐nitrido carbonate (onc) entity. Because the latter two complex anions have...
Wegen der einzigartigen Fähigkeit des Kohlenstoffs, verschiedenste sp‐Hybridisierungen oder Orbitalmischungen auszubilden, kann er in unterschiedlichen komplexen Anionen wie der bekannten Carbodiimideinheit NCN2−, dem bis dato unbekannten CN35−‐Guanidinatanion und dem ebenso neuartigen CN48−‐Orthonitridocarbonat (onc) vorliegen und insofern das Feld bekannter stickstoffbasierter Festkörperverbindungen...
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