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A ruthenium-containing polyoxometalate Rb 8 K 2 [{Ru 4 O 4 (OH) 2 (H 2 O) 4 }(γ-SiW 10 O 36 ) 2 ]·25H 2 O (RuSiW 10 ) with two redox-active centers of Ru and W was assembled on quartz, and ITO by the layer-by-layer self-assembly method. The regular assembled process was monitored by collecting UV–vis spectra...
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