Journal of Electroanalytical Chemistry

Items from 1 to 20 out of 10 993 results

article

Heterogeneous catalytic reaction at a methylene blue/Nafion® modified carbon fiber microcylinder electrode

Huangxian Ju, Yigang Xun, Hongyuan Chen

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 283-285

article

Investigation of the kinetics of assisted potassium ion transfer by dibenzo-18-crown-6 at the micro-ITIES by means of steady-state voltammetry

P.D. Beattie, A. Delay, H.H. Girault

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 167-175

Micropipettes, with internal tip diameters ranging from 1.2 to 38 μm, were fabricated using borosilicate glass capillaries. These were then used to support a micro-interface between two immiscible electrolyte solutions (micro-ITIES). The assisted ion transfer of potassium from water to 1,2-dichloroethane by the neutral ionophore dibenzo-18-crown-6 was followed using both cyclic voltammetry and chronoamperometry...

article

Structural effects in electron transfer reactions: comparative interfacial electrochemical kinetics for cis- versus trans-dioxorhenium(V)(bi)pyridine oxidation

Xiao Lian Zhang, Joseph T. Hupp, Gerald D. Danzer

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 229-235

The comparative interfacial oxidation kinetics of the approximate structural isomers trans-(O) ₂ Re ^V (py) ⁺ ₄ and cis-(O) ₂ Re ^V (bpy)(py) ⁺ ₂ (py, pyridine; bpy, 2,2′-bipyridine) have been assessed in aqueous solution via conventional cyclic voltammetry at a highly ordered pyrolytic graphite (HOPG) electrode. HOPG was employed because of its...

article

Voltammetric behavior of positively charged species at a pyrolytic graphite electrode modified with lauric acid

Josef Hanzli´k, Pierre Bianco, Jean Haladjian

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 287-290

article

Electropolymerized films of isocyanide-functionalized anilines: incorporation of a heavy metal cation into polyanilines

Andrew G. Sykes, Yining Shi, T.Randy Dillingham, Timothy L. Porter, more

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 139-145

The techniques of cyclic voltammetry, X-ray photoelectron spectroscopy and atomic force microscopy (AFM) were used to study the electrochemical generation and characterization of isocyanide-functionalized polyaniline thin films. 3-Isocyanoaniline 1, [Ir(3-isocyanoaniline) ₄ ]PF ₆ and [Ir(4-isocyanoaniline) ₄ ]PF ₆ , formed yellow-gold, well adherent thin films when...

article

Electrochemical reduction of 1,4-dihalobutanes at carbon cathodes in dimethylformamide

Wayne A. Pritts, Dennis G. Peters

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 147-160

Cyclic voltammetry and controlled-potential electrolysis have been employed to investigate the electrochemical behavior of 1,4-dibromo-, 1,4-diiodo-, 1-bromo-4-chloro- and 1-chloro-4-iodobutane at glassy carbon cathodes in dimethylformamide containing tetramethylammonium perchlorate. Depending on the identity of the 1,4-dihalobutane electrolyzed and the choice of potential, reduction of these compounds...

article

Voltammetry in low temperature liquid solutions and frozen media: hexacyanoferrate(II/III) redox system in aqueous LiCl solutions at temperatures between 170 K and 300 K

Kazuko Tanaka, Reita Tamamushi

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 279-282

article

SERS study of the interaction of thiourea with a copper electrode in sulphuric acid solution

G.M. Brown, G.A. Hope, D.P. Schweinsberg, P.M. Fredericks

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 161-166

The electrochemical interaction of thiourea with a copper electrode in sulphuric acid solution was investigated using Fourier transform Raman and in situ surface-enhanced Raman scattering (SERS) spectroscopy. SERS spectra of thiourea at a copper electrode were obtained in solutions containing greater than 5 ppm thiourea; the spectra obtained were consistent with adsorption of the molecule on the copper...

article

Kinetic and diffusional limitations to the anodic dissolution of p-Si in fluoride media

Hamdy H. Hassan, J.L. Sculfort, M. Etman, F. Ozanam, more

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 55-61

The anodic dissolution of single-crystal p-Si in fluoride media in a large range of pH and nominal fluoride concentration c _F has been studied using a rotating-disc electrode. The process is found to be under mixed control, and the measured current is split into kinetic and diffusional contributions. A zero diagram for both kinetic and diffusion currents as a function of c _F , pH and...

article

Anodic oxidation of 9,9′-bifluorenylidene: electrochemical behaviour and physicochemical properties of relevant polymers

J. Rault-Berthelot, H. Le Deit, M. Massaoudi, J. Simonet

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 237-247

The physicochemical properties and electrochemical behaviour of polymers obtained by the anodic oxidation of the 9,9′-bifluorenylidene are presented together with the polymerization conditions.

article

Subject index

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 297-300

article

Electrochemistry of oxo-bridged ruthenium dimers with 4,4′-dichloro- and 5,5′-dichloro-2,2′-bipyridine and their catalytic properties towards water oxidation

Yip-Kai Lai, Kwok-Yin Wong

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 193-200

Ruthenium μ-oxo dimers with chloro-substituted 2,2′-bipyridines [L ₂ (H ₂ O)Ru ^III ORu ^III (OH ₂ )L ₂ ] ⁴⁺ (L= 4,4′-dichloro- or 5,5′-dichloro-2,2′-bipyridine) were synthesized. Electrochemical studies on the complexes showed that the Ru ^III |O|Ru ^III dimer undergoes a reversible one-electron oxidation to Ru ^III |O|Ru...

article

Adsorption of ethyl xanthate anions on a silver electrode. An in-situ FTIR study

G. Sundholm, P. Talonen

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 261-267

The adsorption of ethyl xanthatc ion (EX ⁻ ) on a silver electrode in sodium sulphate, phosphate buffer (pH 6.8) and borate buffer (pH 9.2) solutions was studied in situ using Fourier transform IR reflection spectroscopy. The measurements were carried out using a thin-layer flow cell, which allows a continuous supply of the electroactive species into the thin layer. The voltammetric behaviour...

article

Cyclic voltammetry of Pd+D codeposition

S. Szpak, P.A. Mosier-Boss, S.R. Scharber, J.J. Smith

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 1-6

Processes associated with the Pd+D alloy codeposition are examined by cyclic voltammetry. The voltammograms cover the potential range: +0.3 to −1.3 V (measured against an Ag/AgCl/KCl (sat) reference) and indicate that the partial current due to the Pd ²⁺ ion reduction is diffusion limited at slow scan rates. Except for the significant increase in cathodic currents due to D ₂ O reduction...

article

Spectroelectrochemical detection of phenothiazine and phenoxazine derivatives covalently bound to self-assembled cystamine monolayers

Daniela D. Schlereth, Hanns-Ludwig Schmidt

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 117-125

The phenothiazine derivatives, Toluidine Blue O and Azur A, and the phenoxazine derivative Nile Blue were bound covalently to self-assembled cystamine monolayers chemisorbed on gold electrodes by derivatization of the surface amino groups with two different bifunctional spacers: terephthaloyl chloride and 1,6-hexamethylene-diisocyanate.The formation of the amido- and urea-derivatives of the parent...

article

Editorial Board

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > iii

article

Chronoamperometric response of the cell ITO|HxWO3|PEO-H3PO4(MeCN)|ITO

Malcolm D. Ingram, John A. Duffy, Paul M.S. Monk

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 77-82

Electrochromic devices of the general type indium tin oxide (ITO)|WO ₃ |polyethylenc-oxide (PEO)-H ₃ PO ₄ |(H)ITO were constructed. The mechanism of electrocoloration involves protons decanting from the pre-intercalated ITO to form the cell ITO|H _x WO ₃ |PEO-H ₃ PO ₄ |ITO. During potentiostatic coloration, the current goes through a minimum and...

article

Electrochemical reduction of the bis(cyclo-octadiene)rhodium monocation: generation and fate of the 17-electron radical

Joseph Orsini, William E. Geiger

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 83-90

The electrochemical reduction of the monocation of bis-(cyclo-octadiene)Rh[(COD) ₂ Rh ⁺ ] has been studied in chlorinated hydrocarbons and d ₆ -acetone by cyclic voltammetry, chronoamperometry and exhaustive coulometry. Successive one-electron reductions are observed for the couples (COD) ₂ Rh ⁺ /(COD) ₂ Rh and (COD) ₂ Rh/(COD) ₂ Rh ...

article

Electrochemical study of isopoly and heteropoly anion transfer across the water | nitrobenzene interface. Part II. Vanadium-containing heteropolytungstate anions

Hanming Wang, Zemu Yu, Enbo Wang, Erkang Wang

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 69-75

The electrochemical transfer behaviour of vanadium-containing heteropolytungstate anions [PW _12−x V _x O ₄₀ ] ^(3+x)− (x = 1−4) across the water | nitrobenzene interface has been investigated by cyclic voltammetry and chronopotentiometry with cyclic linear current scanning. The transfer of PW ₁₁ V ₁ O ⁴⁻ ₄₀ , HPW ₁₀ V ₂ O ...

article

Electrocatalytic oxidation of aliphatic diols on platinum and gold Part I: Effects of chain length and isomeric position

A. Hilmi, E.M. Belgsir, J.M. Le´ger, C. Lamy

Journal of Electroanalytical Chemistry > 1995 > 380 > 1-2 > 177-184

The electrochemical reactivity of propanediol, butanediol, pentanediol, hexanediol and heptanediol, on polycrystalline platinum and gold electrodes, was studied in acid and alkaline media. The effect of the number of carbon atoms, i.e. the chain length, was observed. The apparent energies of activation were evaluated systematically and discussed in relation to the molecular structure of the different...

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Keywords

CYCLIC VOLTAMMETRY (692)
ELECTROCATALYSIS (399)
VOLTAMMETRY (358)
ELECTRODEPOSITION (350)
ADSORPTION (328)
ELECTROCHEMISTRY (229)
PLATINUM (180)
ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY (161)
ELECTROPOLYMERIZATION (151)
SPECTROELECTROCHEMISTRY (140)
OXYGEN REDUCTION (136)
IMPEDANCE (134)
OXIDATION (131)
CHRONOAMPEROMETRY (128)
KINETICS (125)
POLYPYRROLE (125)
ELECTROCHEMICAL SENSOR (122)
MODIFIED ELECTRODE (122)
COPPER (121)
ELECTRON TRANSFER (120)
DOPAMINE (119)
HYDROGEN PEROXIDE (113)
POLYANILINE (108)
GRAPHENE (106)
ASCORBIC ACID (100)
BIOSENSOR (100)
IMPEDANCE SPECTROSCOPY (92)
OXYGEN REDUCTION REACTION (92)
SELF-ASSEMBLED MONOLAYERS (87)
SELF-ASSEMBLED MONOLAYER (86)
GOLD (82)
MODIFIED ELECTRODES (82)
CONDUCTING POLYMER (80)
EIS (80)
ION TRANSFER (80)
PHOTOELECTROCHEMISTRY (80)
SUPERCAPACITOR (80)
ELECTROREDUCTION (79)
SIMULATION (79)
DIGITAL SIMULATION (78)
UNDERPOTENTIAL DEPOSITION (77)
FUEL CELL (75)
MICROELECTRODES (75)
ELECTROCHEMICAL OXIDATION (74)
GOLD NANOPARTICLES (74)
REDUCTION (74)
CARBON NANOTUBES (73)
DIFFUSION (73)
URIC ACID (73)
DIFFERENTIAL PULSE VOLTAMMETRY (70)
ELECTRO-OXIDATION (69)
ANODIC OXIDATION (68)
GLUCOSE (68)
MICROELECTRODE (68)
SQUARE WAVE VOLTAMMETRY (67)
FERROCENE (65)
GOLD ELECTRODE (65)
SILVER (65)
ELECTROCATALYTIC OXIDATION (64)
PALLADIUM (64)
CONDUCTING POLYMERS (63)
EQCM (63)
IONIC LIQUID (62)
GLASSY CARBON (61)
ITIES (61)
AC IMPEDANCE (60)
CARBON MONOXIDE (60)
CORROSION (60)
DIFFUSION COEFFICIENT (60)
ELECTROCHEMICAL REDUCTION (60)
NUCLEATION (59)
ELECTROCHEMILUMINESCENCE (58)
BIOSENSORS (56)
CARBON PASTE ELECTRODE (56)
CHEMICALLY MODIFIED ELECTRODE (56)
AMPEROMETRY (53)
METHANOL (53)
REACTION MECHANISM (53)
XPS (53)
ELECTROCHEMICAL QUARTZ CRYSTAL MICROBALANCE (51)
ELECTROCHROMISM (49)
GLUCOSE OXIDASE (49)
HYDROGEN EVOLUTION (49)
SELF-ASSEMBLY (49)
CYTOCHROME C (48)
CAPACITANCE (47)
MECHANISM (47)
REDUCED GRAPHENE OXIDE (46)
AU(111) (45)
ELECTROCATALYST (45)
NANOPARTICLES (45)
CATALYSIS (44)
ELECTROOXIDATION (44)
ELECTROSORPTION (44)
GRAPHENE OXIDE (44)
BISMUTH (43)
METHANOL OXIDATION (43)
NAFION (43)
ROTATING DISK ELECTRODE (43)
SCANNING TUNNELING MICROSCOPY (43)
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Journal of Electroanalytical Chemistry

Heterogeneous catalytic reaction at a methylene blue/Nafion® modified carbon fiber microcylinder electrode

Investigation of the kinetics of assisted potassium ion transfer by dibenzo-18-crown-6 at the micro-ITIES by means of steady-state voltammetry

Structural effects in electron transfer reactions: comparative interfacial electrochemical kinetics for cis- versus trans-dioxorhenium(V)(bi)pyridine oxidation

Voltammetric behavior of positively charged species at a pyrolytic graphite electrode modified with lauric acid

Electropolymerized films of isocyanide-functionalized anilines: incorporation of a heavy metal cation into polyanilines

Electrochemical reduction of 1,4-dihalobutanes at carbon cathodes in dimethylformamide

Voltammetry in low temperature liquid solutions and frozen media: hexacyanoferrate(II/III) redox system in aqueous LiCl solutions at temperatures between 170 K and 300 K

SERS study of the interaction of thiourea with a copper electrode in sulphuric acid solution

Kinetic and diffusional limitations to the anodic dissolution of p-Si in fluoride media

Anodic oxidation of 9,9′-bifluorenylidene: electrochemical behaviour and physicochemical properties of relevant polymers

Subject index

Electrochemistry of oxo-bridged ruthenium dimers with 4,4′-dichloro- and 5,5′-dichloro-2,2′-bipyridine and their catalytic properties towards water oxidation

Adsorption of ethyl xanthate anions on a silver electrode. An in-situ FTIR study

Cyclic voltammetry of Pd+D codeposition

Spectroelectrochemical detection of phenothiazine and phenoxazine derivatives covalently bound to self-assembled cystamine monolayers

Editorial Board

Chronoamperometric response of the cell ITO|HxWO3|PEO-H3PO4(MeCN)|ITO

Electrochemical reduction of the bis(cyclo-octadiene)rhodium monocation: generation and fate of the 17-electron radical

Electrochemical study of isopoly and heteropoly anion transfer across the water | nitrobenzene interface. Part II. Vanadium-containing heteropolytungstate anions

Electrocatalytic oxidation of aliphatic diols on platinum and gold Part I: Effects of chain length and isomeric position

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