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Mixed valence cyanide bridged polynuclear complexes of formula [Fe II (CNFe III L) 6 ] x+ , where L is a pentadentate ligand, may be considered as structural models for Prussian Blue. A judicious choice of the peripheral ligand allows us to tune their electronic and magnetic properties. A correlation between the nature of the peripheral ligand and...
The synthesis of the new organoiron salt [(η 5 -C 5 Me 5 )(η 2 -dppe)Fe-C=C-2,5-C 4 H 2 S-C=C-Fe(η 2 -dppe)(η 5 -C 5 Me 5 ) ][PF 6 ] 2 -(4[PF 6 ] 2 , dppe = 1,2-bis(diphenylphosphino)ethane) is reported with its full spectroscopic characterizations ( 1 H and 31 P NMR,...
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