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Glycoside hydrolase (GH) family 65 contains phosphorylases acting on maltose (Glc‐α1,4‐Glc), kojibiose (Glc‐α1,2‐Glc), trehalose (Glc‐α1,α1,‐Glc), and nigerose (Glc‐α1,3‐Glc). These phosphorylases can efficiently catalyze the reverse reactions with high specificities, and thus can be applied to the practical synthesis of α‐glucosyl oligosaccharides. Here, we determined the crystal structures of kojibiose...
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