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The Cover Feature shows the bis(tridentate Schiff base Pt(II)) complex containing dimethyl sulfoxide (Pt2L2DMSO) as a combination of yellow disks, gray disks, orange cones, and a black curved line. Pt2L2DMSO is unfolding due to the steric repulsion of the bulky ligand. The blue hexagons connected to the branched black lines stand for poly(4‐vinylpyridine) (P4VP). The green curved figure in the background...
Redox‐active tungsten alkyne complex‐based phosphines of the type [Tp*W(CO)Br(η2‐C2(PR2)x] (x=1, 2; R=Ph, i‐Pr) and coordination experiments with the corresponding diphosphines are described. The pKB values of the terminal free phosphine groups were estimated indirectly by the 1JP/Se coupling constants in the associated P‐selenides. A ten orders of magnitude higher basicity for the bis(diisopropyl)phosphine...