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The advantages of Fourier-Transform infrared (FTIR) spectroscopy over conventional dispersive instrumentation have revitalized the utilization of vibrational spectroscopy in polymer research. In the field of rheo-optics primarily the rapid-scanning capability of the FTIR technique has contributed to a more detailed insight into the technologically important process of polymer deformation. It is the...
In this review, the fine structure of polymers obtained by radiation-induced polymerization in the solid state, i.e., poly(tioxane) and poly(tetroxocane), is characterized by X-ray scattering, melting behavior, and radiolysis. The annealing effects on these behaviors gave quite valuable information to clarify the fine structure of the original material, since the materials used here are crystalline...
The most general molecular theory of rubberlike elasticity is reviewed as a preliminary to its use in the interpretation and understanding of the moduli of model elastomeric materials, i.e., polymer networks prepared in such a way that their structure is relatively well known. Applications are made to both perfect and imperfect networks, with critical evaluation of evidence possibly attributable to...
To improve our understanding of the vast variety of structural and functional features of peptides and proteins theoretical and experimental investigations of the interrelation between sequence, structure and function are necessary. This article reviews recent contributions to this field. First, the most popular methods for secondary structure prediction are discussed. In the light of the accuracy...
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