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A two‐dimensional finite difference numerical model was developed to describe the transport of dissolved organics originating from nonaqueous phase liquid (NAPL) pool dissolution in saturated porous media in the presence of dissolved humic substances. A rectangular NAPL pool was considered in a homogeneous porous medium with unidirectional interstitial groundwater velocity. It was assumed that dissolved...
Local mass transfer correlations are developed to describe the rate of interface mass transfer of single component nonaqueous phase liquid (NAPL) pools in saturated subsurface formations. A three‐dimensional solute transport model is employed to compute local mass transfer coefficients from concentration gradients at the NAPL–water interface, assuming that the aqueous phase concentration along the...
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