The infrared spectrum of the ionic cluster I - (H 2 O) was recorded from 3170 to 3800 cm - 1 by vibrational predissociation spectroscopy. A strong multiplet observed at 3415 cm - 1 and a narrow band at 3710 cm - 1 were assigned as a hydrogen-bonded OH stretch and free OH stretch respectively, indicating that H 2 O forms a single hydrogen bond with the iodide anion. Ab initio vibrational frequencies and intensities were computed at the second-order M ller-Plesset (MP2) level for the minimum energy configuration, a nearly linear hydrogen-bonded isomer, and for a low-lying saddlepoint, a symmetric C 2 v bridged isomer. The spectrum predicted for the hydrogen-bonded isomer agreed well with experiment.