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The irreversible adsorption of Sn on the three Pt basal planes (Sn/Pt(111), Sn/Pt(100) and Sn/Pt(110)) and the oxidation of adsorbed carbon monoxide have been studied by cyclic and stripping voltammetry. The presence of Sn adatoms blocks the adsorption of hydrogen on platinum, and leads to the observation of a new oxidation peak ascribed to the four-electron oxidation of the Sn adatom at potentials...
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