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Irreversible adsorption of oxocarbons on bismuth and selenium modified Pt(111) electrodes has been examined by cyclic voltammetry and in situ FT-IR spectroscopy. A simple third-body effect is observed in the adsorption of those oxocarbons giving rise to only one adsorbed residue: squaric acid which is dissociatively adsorbed to CO adsorbates and tetrahydroxy-p-benzoquinone which is directly adsorbed...
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