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The bi-functional mechanism has been widely accepted for describing the binary catalysts in methanol electrooxidation, in which Pt sites can catalyze the methanol dehydrogenation and the second elements (e.g. Ru, Sn) can activate water to oxidants. However, in terms of binary PtRh, the surface Rh sites being identified not to be oxidized as easily as Ru, may participate in the dehydrogenation reaction...
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