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Electroreduction behavior of three dibromobenzenes (1) has been investigated by cyclic voltammetry on glassy carbon and silver electrodes in DMF in the absence and presence of CO 2 . For meta- and para-dibromobenzenes, two successive two-electron reduction peaks could be detected, attributed to sequential cleavage of two reductive C–Br bond, while most of ortho-dibromobenzene underwent four-electron...
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