Chiral Ansa Zirconocene Compounds with [Me 2 Si] and [Me 4 Si 2 ] Bridges and with tert -Butyl Ring Substituents: Synthesis and Structural Characterization of the Racemo Complexes r ac - [Me 2 Si(C 5 H 2 -2,4-Bu t 2 ) 2 ]ZrCl 2 and r ac - [Me 4 Si 2 (C 5 H 2 -2,4-Bu t 2 ) 2 ]ZrCl 2