Does α-Fluorination Affect the Structural trans- Influence and Kinetic trans- Effect of an Alkyl Ligand? Molecular Structures of Pd(TMEDA)(CH 3 )(R F ) and a Kinetic Study of the trans to cis Isomerization of Pt(TMEDA)(CH 3 ) 2 I(R F ) [R F = CF 2 CF 3 , CFHCF 3 , CH 2 CF 3 ]