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The electrode reaction of the Pu 3+ /Pu couple at the surface of a liquid Cd electrode was investigated by cyclic voltammetry at 723, 773 and 823 K in LiCl KCl eutectic melt. It was found that the diffusion of Pu 3+ in the salt phase was a rate-determining step in the cathodic reaction, but the dissolution of Pu from the liquid Cd phase was so slow that the anodic wave broadened...
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