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Voltammetric studies have been conducted on chlorobis[2-(2'-hydroxyphenyl)-2-oxazolinato]oxorhenium(V) (1, (hoz) 2 Re(O)Cl) and related complexes. These complexes are potentially useful catalysts for the conversion of perchlorate to chloride using chemical reductants such as sulfides. The possible use of an electrode as the reducing agent in the catalytic cycle is explored here. In anhydrous...
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