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Infrared spectroscopy of adsorbed hydroxide (OHad) has been performed on the high index planes of Pt: n(111)–(100) and n(111)–(111) series. The bending mode of OHad (δPtOH) appears on these surfaces around 1080cm−1, which is similar to the result on the low index planes of Pt. The band intensity of δPtOH depends on surface structure and electrode potential. At 0.9V vs RHE, the band intensity of δPtOH...
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