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Photosubstitutionally active ruthenium complexes show high potential as prodrugs for the photoactivated chemotherapy (PACT) treatment of tumors. One of the problems in PACT is that the localization of the ruthenium compound is hard to trace. Here, a ruthenium PACT prodrug, [Ru(3)(biq)(STF‐31)](PF6)2 (where 3 = 3‐(([2,2′:6′,2″‐ter‐ pyridin]‐4′‐yloxy)propyl‐4‐(pyren‐1‐yl)butanoate) and biq = 2,2′‐biquinoline),...