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Polymer structure of a block copolymer of poly(l‐lactic acid) (PLLA) and polystyrene (PS) is formed among a fibrous structure of PLLA inducing the gelation of PLLA in N,N‐dimethylformamide (DMF). The results of static and dynamic light scattering show the formation and growth of aggregates of the block copolymer (PLLA‐b‐PS) to form aggregates in DMF. The gels formed by the fibrous structure of PLLA...