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The reaction between 3,6,9‐trithia‐1(2,6)‐pyridinacyclodecaphane and representative group 10 and 11 metal salts [Cu(NO3)2, NiCl2 or Ag(CF3CO2)] afforded 1:1 complexes, which in the case of CuII and AgI were characterised by single‐crystal X‐ray crystallography. The catalytic activity of these complexes in A3‐coupling reactions between aldehydes, terminal alkynes and amines was assessed in both protic...
Oxidative stress (OS) plays a central role in the progression of liver disease and in damage to liver by toxic xenobiotics. We have developed methods for noninvasive assessment of hepatic OS defenses by measuring flux through the glutathione (GSH) synthesis pathway. 13C‐labeled GSH is endogenously produced and detected by in vivo magnetic resonance after administration of [2‐13C]‐glycine. We report...
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