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Treatment of [Ru(COD)(MeAllyl)2] and [Ru(COD)(COT)] with GaCp* under hydrogenolytic conditions leads to reactive intermediates which activate Si−H or C−H bonds, respectively. The product complexes [Ru(GaCp*)3(SiEt3)H3] (1) and [Ru(GaCp*)3(C7H7)H3] (2) are formed with HSiEt3 or with toluene as the solvent, respectively. While 1 was isolated and fully characterized by NMR, MS, IR and SC‐XRD, 2 was too...