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A triangular‐prism shaped cage was self‐assembled by the formation of a dynamic covalent bond, namely a hydrazone, in acidic aqueous solution. The hexacationic host bears a number of relatively acidic protons pointing inside the cage cavity, which is able to accommodate an iodide anion selectively in water over other halide anions such as F−, Cl−, and Br−, which are more hydrated. As a comparison,...
A triangular‐prism shaped cage was self‐assembled by the formation of a dynamic covalent bond, namely a hydrazone, in acidic aqueous solution. The hexacationic host bears a number of relatively acidic protons pointing inside the cage cavity, which is able to accommodate an iodide anion selectively in water over other halide anions such as F−, Cl−, and Br−, which are more hydrated. As a comparison,...
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