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Length‐Modulated Azide Photocrosslinker
In article 2212127, Kilwon Cho, Boseok Kang, and co‐workers, report a series of length‐modulated azide photocrosslinkers (n‐NIPS) that improve stretchability and charge transport retention in thin films of conjugated polymers. Especially, the shortest photocrosslinker, 1‐NIPS, is demonstrated to enhance these properties, even up to 80% unidirectional tensile...
To impart high stretchability to semiconducting polymers, researchers have used a photocrosslinking approach based on the nitrene chemistry of an azide‐incorporated molecular additive. However, understanding of the molecular design of azide crosslinkers with respect to their effects on the electrical and mechanical properties of semiconducting polymer thin films is lacking. In this study, the effects...
TaS2 nanolayers with reduced dimensionality show interesting physics, such as a gate‐tunable phase transition and enhanced superconductivity, among others. Here, a solution‐based strategy to fabricate a large‐area foil of hybrid TaS2/organic superlattice, where [TaS2] monolayers and organic molecules alternatively stack in atomic scale, is proposed. The [TaS2] layers are spatially isolated with remarkably...
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