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ZrW2O8 is known as a negative coefficient of thermal expansion (CTE) material. In contrast, the studies of other properties than the CTE of ZrW2O8, such as thermal conductivity and mechanical properties, are limited. Herein, a highly dense bulk sample (%T.D. > 95%) of ZrW2O8 from very fine powder (D50 0.3 μm) with a crystalline size of 31 nm using a spark plasma sintering (SPS) technique is synthesized...