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Silicon-rich nitride nanocomposites with stable multicolour photoluminescence (PL) are developed in this work. Firstly, a single PL band can be adjusted in the visible spectral range. Secondly, simultaneous emission of an additional PL band is achieved due to boron-doping of the nanocomposites. Impact of thermal annealing of the silicon nitride films in different atmospheres at various temperatures...