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N,N-Diethyldithiocarbamate functionnalized 1,4-polyisoprenes were prepared from 1,4-polyisoprenes (natural or synthetic). The syntheses were performed by nucleophilic addition of N,N-diethyldithiocarbamate salts upon oxirane rings of epoxidized units according to a SN2 mechanism with ring opening. Studies on model molecules of epoxidized 1,4-polyisoprene units (1,2-epoxy-1-methylcyclohexane and 4,5-epoxy-4-methyloctane)...
A membrane photonic crystal cavity coupled to a waveguide is fabricated and characterised. Fabry-Perot method was used to measure propagation losses. We show that coupling results in asymmetric features in the transmission suitable for high-speed analog modulation.
The group delay in low-loss, single-mode, 1-mm-long photonic crystal slab waveguides is measured using the phase-shift technique. Slow modes appear a promising approach for compact and massively integrated optical delay lines for signal processing.
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