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The synthesis of the LTA-type aluminophosphate could be achieved from aqueous reaction mixtures in the presence of a single organic template, i.e. the hexacosa-4,7,13,16,21,24-diaza-1,10-bicyclo[8,8,8]hexacosane ( Kryptofix222 ), this organic species being occluded in the large α cage of the structure. When F - ions were added in the synthesis medium, they acted as co-templates and were...