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Rh supported catalysts were prepared by impregnating rhodium(I) and rhodium(III) complexes with and without heteropolyacids for the hydroformylation of styrene derivatives. The effect of the pore size of MCM-41 was considered. The addition of water showed a promoting effect with Rh(III) based catalysts. The amount of water showed also a big effect on the catalytic activity of the Rh(III) supported...