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The syntheses and properties of the Ni(II) complex [Ni(sac)(bipy) 2 (H 2 O)].sac (3) (sacH=saccharin, bipy=2,2'-bipyridine) and crystal structural studies of 3 and two other related derivatives [Zn(sac)(bipy) 2 (H 2 O)].sac (5) and [Cd(sac) 2 (bipy) 2 ] 6 are described. The Ni and Zn complexes belong to an isostructural series along with the corresponding...