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In this paper, it is proposed a new route, named “Alkoxycle”, for the conversion of glycerol from biodiesel production into H2 and CO/CO2 in different and separate stages. In this process, glycerol first reacts with NaOH to form an alkoxide that, in a second step, undergoes controlled thermal decomposition. Analyses of glycerol:NaOH precursor mixtures (molar ratios of 1:1, 1:2, 1:3 and 1:5) by TG,...
In this work, it was investigated the conversion of fatty acids into hydrocarbon based on the reaction with NaOH followed by a controlled thermal decomposition. FTIR, Raman, UV–vis, XRD, TG-MS, SEM/TEM, CHN, GC–MS showed that precursors based on NaOH/oleic acid (molar ratios 0.7, 1.0, 1.5 and 2.0) decomposed at 550°C to produce three fractions, i.e. liquid (5–37wt%), gas (52–70wt%) and solid (10–31wt%)...
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