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Formation of B3H7 species from the protonation of B3H8− has been studied by ab initio calculations at the HF and correlated MP2 levels using extended basis set 6-31+G∗∗. Two elementary processes, B3H8−+H+→B3H9 and B3H9→B3H7+H2, have been investigated. The calculated absolute values of B3H8−+H+→B3H9 protonation energy are very high (above 314kcalmol−1). Loss of molecular hydrogen from B3H9 proceeds...
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