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Using microkinetic modeling, we have determined the closed catalytic cycle that describes the water gas shift reaction on copper catalysts. Eight elementary reactions constitute the cycle. Dissociation of water and the recombination of surface hydrogen result in dihydrogen. While surface hydroxyl reacts with surface CO to give a surface carboxyl intermediate, which, in turn, reacts with another surface...
The catalytic performance of cobalt catalysts supported on γ-Al 2 O 3 , TiO 2 , ZrO 2 were studied for bio-ethanol steam reforming (BESR) reaction. The supported catalysts (10wt%Co) were prepared by impregnation and characterized through Thermogravimetric analysis (TGA), H 2 chemisorption, laser Raman Spectroscopy, Diffuse Reflectance Infrared Fourier Transform...
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