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Three zinc complexes ([(DMOX)ZnX2], X = Cl (1), Br (2) or I (3)), where DMOX is 4,5-dihydro-2-(4,5-dihydro-4,4-dimethyloxazol-2-yl)-4,4-dimethyloxazole), have been fully characterized by single crystal X-ray diffraction, UV–vis, NMR and IR spectroscopy. Moreover, all zinc complexes showed activities in catalyzing hydrolysis of 4-nitrophenyl acetate (4-NA). And active species have been determined by...