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Multiferroic and photovoltaic properties of polycrystalline Bi0.85Ca0.15FeO3 (BCFO) film on refined Pt(111) electrode buffered glass substrate have been studied. Optimized Pt(111) electrode layer having large grain size and smooth morphology enables the development of highly (110)-textured BCFO film at a temperature as low as 450°C. The prepared BCFO film has dense microstructure, fine grain size,...