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A functional [C4mimCl]CoCl2 ionic liquid was prepared by directly mixing cobalt chloride (CoCl2) with 1-n-butyl-3-methylimidazolium chloride (C4mimCl). Oxone (KHSO5) was selected as an oxidizing agent and, together with [C4mimCl]CoCl2, formed an extraction/catalytic oxidation system for the desulfurization of fuels. Compared with the Fenton-like desulfurization systems, the oxone solid is cheaper,...