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It was observed that Ba(BrF 4 ) 2 demonstrates a high reactivity towards n-hexane. It was found that the heating the reaction mass proceed with intensive self-heating up to 40°C and release of elemental bromine. The GC-MS analysis showed that the main product of Ba(BrF 4 ) 2 interaction with n-hexane is 3-bromohexane. The optimal interaction parameters were found. The...
This paper is devoted to the problems of application of alkali and alkaline-earth metal tetrafluorobromates in organic synthesis. The process of Halon 1301 synthesis, which is one of the best fire-extinguishing agents, is considered.
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