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A new dithiocarbazate ligand, S-2-picolyldithiocarbazate (S2PDTC) was synthesized using 2-picolylchloride hydrochloride. Tridentate Schiff bases were prepared by condensation of S-2-picolyldithiocarbazate (S2PDTC) with pyridine-2-carboxaldehyde (NNS ' ), 2-acetylpyrrole (NNS'') and 2-acetylthiophene (NSS), while a bidentate Schiff base (NS) was prepared by condensing the S2PDTC with 2-acetylfuran...
A tridentate Schiff base having HNNS donor sequence was prepared by condensing S-benzyldithiocarbazate (NH 2 NHCSSCH 2 Ph) with pyridine-2-carboxaldehyde. Complexes of this ligand, pyCHNNHCSSCH 2 Ph(HNNS), with Cu(II), Cd(II) and Zn(II) were synthesized and characterized by elemental analyses and various physico-chemical techniques. X-ray crystallographic analysis shows that...
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