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New derivatives of fullerenes C60 and C70 containing triazole and deoxythymidine fragments are obtained by the Bingel–Hirsch and ‘click-chemistry’ reactions from acetylene methanofullerene and azido thymidine derivatives.
New mono- and hexa-methanofullerenes containing different number of acetonide groups are synthesized and characterized. Removing the acetonide protection leads to new chromatographically pure water-soluble polyol methanofullerenes with essentially quantitative yields.
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