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The main crystallization trends of complex oxide compounds of lanthanides from alkaline phosphate-molybdate (tungstate) melts have been studied in light of structure - luminescence properties relationships. The regions of formation MI3Ln(PO4)2, LnPO4, K2Ln(PO4)(MVIO4), MIMIII(MVIO4)2 from self flux systems MI-P-Ln-O (MI-alkaline metal; MVI-Mo, W) have been defined. The influence of MI/MVI ratio in...
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