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The photodissociation dynamics of ClONO 2 at 235nm has been reinvestigated using velocity map ion imaging. We report branching ratios for the Cl+NO 3 and ClO+NO 2 channels to be 0.49:0.51 with anisotropy parameters of β=0.5±0.1 and β=−0.1±0.3 for the Cl and ClO production channels, respectively. Photodissociation at 248nm and 262nm results in similar branching ratios and dynamics...
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