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A series of dangling chain based-polyurethane/poly(methyl methacrylate) (DPU/PMMA) filled with exfoliated layered double hydroxides (LDH) were synthesized by methyl methacrylate in-situ intercalative polymerization. The dangling chains were introduced by using vegetable oils as chain extender. The effect of dangling chain and the contents of LDH on the molecular dynamics of DPU/PMMA was investigated...
The dynamic rheological properties and morphology in the vicinity of phase-separated region for poly(methyl methacrylate) (PMMA)/poly(styrene-co-acrylonitrile) (SAN) blends with lower critical solution temperature (LCST) behavior were investigated. When temperature was above the phase separation temperature, i.e. cloud point (T c ) for some PMMA/SAN blends, the slope of plotting logG′ versus...
On the basis of phase separation temperatures (T s ) for poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) blends of different compositions, measured by small angle laser light scattering, we have studied dynamic rheological behavior of these blends at different temperatures below, near and above T s . The results showed that the time–temperature superposition principle could...
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