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A mixed-monolayer of an antigen and electrocatalyst assembled onto Au surfaces acts as an immunosensor electrode for the amplified amperometric detection of the complementary antibody (Ab). In the presence of a substrate for the electrocatalyst, the mixed monolayer electrode yields an electrocatalytic current which is blocked by association of the Ab to the monolayer. A mixed monolayer of Nε-2,4-dinitrophenyl...
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