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The shuttle effect and sluggish redox kinetics of lithium polysulfides (LiPSs) severely hinder the scalable application of lithium‐sulfurr (Li–S) batteries. Herein, the highly dispersed α‐phase molybdenum carbide nano‐crystallites embedded in a porous nitrogen‐doped carbon framework (α‐MoC1−x@NCF) are developed via a simple metal–organic frameworks (MOFs) assisted strategy and proposed as the multifunctional...