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Toward solar‐to‐hydrogen generation, it is required to assembling an efficient photoelectrode in the solar energy conversion system. The preparation of rGO‐CuO/Cu photoelectrode via a facile one‐pot hydrothermal approach is reported. Here, we present the physicochemical and performance of rGO‐CuO/Cu photoelectrode in different hydrothermal reaction time. The XRD, XPS, HRTEM, FESEM, and Raman analysis...