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The roughness and mechanical properties of ultra‐low profile electrolytic copper foil seriously affect and restrict its application in high‐frequency/high‐speed printed circuit boards and Li‐ion batteries. herein, the electrochemical behavior and mechanism of 3‐N,N‐dimethylaminodithiocarbamoyl‐1‐propanesulfonic acid (DPS), alcohol sulfur propane sulfonate (HP), and hydrolisis animal protein (HAP)...