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A green palladium (Pd)‐based catalyst supported on Rosa canina fruit extract‐modified graphene oxide [Pd nanoparticles (NPs)/reduced graphene oxide (RGO)‐Rosa canina] hybrid materials has been used as a recoverable and heterogeneous nanocatalyst for cyanating aryl halides using K4[Fe (CN)6] as the resource of cyanide. The nitriles were achieved in good to high yield, and the catalyst can be recovered...