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Electrical and optical phenomena in the process of combustion of heterogeneous energetic condensed systems (ECSs) of the (Zr + CuO + LiF)–(Zr + BaCrO4 + LiF) type that represent the model of a high-temperature electrochemical cell (HEC) are experimentally investigated. It is found that combustion of the systems studied generates a pulsed electrical signal with a half-width duration of ~1.0 s. The...