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Bimetallic sulfide hydrodearomatization–hydrodesulfurization catalysts based on mesoporous organic supports made of phenol-formaldehyde resins (MPF) and porous aromatic frameworks (PAFs) have been synthesized. The catalysts exhibit high activity in the hydroconversion of light cycle oil: the sulfur content decreases from 3500 to 390 ppm within 8 h of reaction at a hydrogen pressure of 5 MPa and a...
Nickel–molybdenum sulfide catalysts have been synthesized in situ in a hydrocarbon medium by the decomposition of the [(n-Bu)4N]2Ni(MoS4)2 precursor complex supported on an ordered mesoporous phenol–formaldehyde polymer in the presence of a sulfiding agent (dimethyl disulfide). The catalytic properties of the samples have been studied in a batch reactor at 380°C and a hydrogen pressure of 5.0 MPa...
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