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Characterizing the polar order is a fundamental step in the understanding of a material and a necessity for application purposes since each polar order is associated with specific functionalities. Here, using the Pb(Yb $$_{1/2}$$ 1 / 2 Nb $$_{1/2}$$ 1 / 2 )O $$_3$$ 3 -PbTiO $$_3$$ 3 (PYN-PT) solid solution as an example, we propose to differentiate the...